I'm a bookkeeper, and I've never seen so many postings for accountant/bookkeeper positions for non-profits as I have here in ABQ. There's definitely a bunch here. I suspect the same might also be said for Santa Fe, but again, that's just job postings in my field. On the other hand, from the audits my firm has done, I also suspect many of the non-profits are small (2-5 office staff or all volunteer), not big ones like United Way.
As for the Pastry Arts, if that's the same as a Pastry Chef, he might check out the casino hotels and resort hotels like the Hyatt Regency Tamaya Resort.
Before I moved here, I researched jobs in ABQ on-line and via classifieds, and had the impression it was a tight job market. However, in reality, my experience was vastly different (NO problem finding a job) and I think many of the jobs here never make it on-line or get published in the paper - filled perhaps by networking & referrals and agencies. I read many years ago where less than 20% of all job openings are ever published, and I think that may hold true for ABQ.
Have you tried calling some of the major employment agencies and temp agencies, to get a feel for what you do and the market here? I've sent a resume to agencies in the past prior to relocating and received good advice from them prior to the move. Can't hurt