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Pueblo is not a huge city, and is not in a valley or up against the mountains, so the air quality is pretty good. I would imagine a little bit of smog may be visible along the horizon on cold winter mornings, as it is in Colorado Springs.
Pueblo is known as "The Steel City." The Oregon Steel mill is there... its smoke stacks pretty much dominate the skyline. Also, the state's largest coal fired power plant is on the south edge of town. Its not the most polluted city you'll ever see, but Pueblo has an industrial past, and its pretty obvious.
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