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There can be a whole lot of things involved. If there was lightning, there was ozone. Rain is generally either pH neutral or acid (hose water is pH basic). If the storm had strong winds and updrafts, there could be odors from nearby fields/forests/oceans/lakes/glaciers/bathing beauties.
I've read that it's because of petrichor (see link below).
It is a combination of ozone, petrichor and geosmin (a major contributor to petrichor). I think the ozone in particular is very important, and you can't create it just by watering a lawn.
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