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I felt some chemistry with my SO on our first date. We actually had agreed to meet "just as friends" after developing a friendship online over a long period of time. So it was a little different than a normal first date where you really wouldn't know much about your date.
Howeverm the real sparks were on the second date. We had gone to see a movie, and made it about a third into it before we kissed. Next thing we new, the final credits were rolling!