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TL;DR: He met a 22 year old who was already married with 2 kids trolling on another message board. That 22 year old then left her husband for this guy, and he left his wife. While he calls her "smart" and "hardworking," she seems to grift off of others (her long lost father, for instance) and doesn't seem to have a job or the ability to support herself or her kids.
Even without all the jealousy stuff, she doesn't sound like she has much going for her. Run.
Also, she is , per the OP, "amazing," which I take to mean is considered physically attractive and, when not acting in an emotionally unstable manner, at least, provides an outlet for sexual release.