Artificial photsynthesis? Why bother?
Mother Nature worked on the problem for billions of years and that probably can't be improved upon by us...When the fossil fuel runs out, just turn biomass into "wood gas"-- ch4 & h2. We already know how...When Paris became the City of Lights in the 19th centruy, they did it with coal gas (also known as Town Gas)-- Same thing...Available right now as Syn Gas
https://www.ahajournals.org/doi/full...53642.34528.d9
The problem with "free" electrolysis of water into h2 is that the h2 is highly caustic and its small molecular size makes it very difficult (ie- expensive) to contain...and it's very dangerous for use in automotive applications (Oh! The Humanity!)...I know I wouldn't want to be Flyin' the Ryan, sharing the road on a Sunday at 3AM with a bunch of drunks driving H-powered cars.